SYNTHESIS OF 1,10,19,28-TETRAOXA-4,7,13,16,22,25,31,34-OCTAAZACYCLOHEXATRIACONTANE (L) AND ITS COMPLEX [CU4L(OH)4][CLO4]4-BULLET-2H2O

被引：13
|
作者：
SHIMADA, T [1 ]
KODERA, M [1 ]
OKAWA, H [1 ]
KIDA, S [1 ]
机构：
[1] KYUSHU UNIV,FAC SCI,DEPT CHEM,HAKOZAKI 6-10-1,HIGASHI KU,FUKUOKA 812,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 07期
关键词：
D O I：
10.1039/dt9920001121
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 36-membered macrocycle with four ethylenediamine entities, 1,1019,28-tetraoxa-4,7,13,1 6,22,25,31,34-octaazacyclohexatriacontane (L), has been synthesized and characterized by H-1 and C-13 NMR and fast atom bombardment (FAB) mass spectra. Its complexing behaviour toward copper(II) ion was investigated spectroscopically and the macrocycle shown to incorporate four copper(II) ions in the range pH 6-9. A tetranuclear complex [Cu4L(OH)4] [ClO4]4.2H2O was obtained and characterized to be of a cubane-type Cu4(OH)4 core surrounded by the macrocycle, according to IR, visible, FAB and ESR spectra, cyclic voltammetry, and cryomagnetic susceptibility.
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收藏
页码：1121 / 1125
页数：5
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