SYNTHESIS OF 1,10,19,28-TETRAOXA-4,7,13,16,22,25,31,34-OCTAAZACYCLOHEXATRIACONTANE (L) AND ITS COMPLEX [CU4L(OH)4][CLO4]4-BULLET-2H2O

被引：13

作者：

SHIMADA, T ^{[1
]}

KODERA, M ^{[1
]}

OKAWA, H ^{[1
]}

KIDA, S ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC SCI,DEPT CHEM,HAKOZAKI 6-10-1,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 07期

关键词：

D O I：

10.1039/dt9920001121

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 36-membered macrocycle with four ethylenediamine entities, 1,1019,28-tetraoxa-4,7,13,1 6,22,25,31,34-octaazacyclohexatriacontane (L), has been synthesized and characterized by H-1 and C-13 NMR and fast atom bombardment (FAB) mass spectra. Its complexing behaviour toward copper(II) ion was investigated spectroscopically and the macrocycle shown to incorporate four copper(II) ions in the range pH 6-9. A tetranuclear complex [Cu4L(OH)4] [ClO4]4.2H2O was obtained and characterized to be of a cubane-type Cu4(OH)4 core surrounded by the macrocycle, according to IR, visible, FAB and ESR spectra, cyclic voltammetry, and cryomagnetic susceptibility.

引用

页码：1121 / 1125

页数：5

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