THE ISOMERIZATION CHLORINATION OF O,O-DIALKYL-PHENYLTHIOPHOSPHONATES WITH PHOSPHORUS OXYCHLORIDE - A NEW CONVENIENT SYNTHESIS OF S-ALKYL-PHENYLTHIOPHOSPHONIC ACID-DERIVATIVES

被引：10

作者：

TANG, CC

WU, GP

HUANG, GY

LI, Z

JIN, GY

机构：

[1] Institute of Elemento-Organic Chemistry, Nankai University

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 84卷 / 1-4期

基金：

中国国家自然科学基金;

关键词：

PHOSPHONOTHIONATE; PHOSPHONOTHIOLATE; PHOSPHONODITHIOLATE; PHOSPHONAMIDOTHIOLATE; ISOMERIZATION; CHLORINATION;

D O I：

10.1080/10426509308034327

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for the synthesis of S-alkyl phenylthiophosphonic acid derivatives is reported. The chlorination of O,O-dialkyl phenylthiophosphonates with phosphorus oxychloride proceeds with isomerization to give S-alkyl phenylthiophosphonochloridates, which react further with various nucleophiles in the presence of triethylamine to give the title compounds.

引用

页码：159 / 164

页数：6

共 23 条

[1] The isomerization chlorination of O,O-dialkyl methylthiophosphonates with phosphorus oxychloride - A new convenient synthesis of S-alkyl methylthiophosphonic acid derivatives
Tang, CC
Ma, FP
Zhang, K
He, ZJ
Jin, YC
HETEROATOM CHEMISTRY, 1995, 6 (05) : 413 - 417
[2] The Isomerization/Chlorination of Nitrogen Heterocyclic O,O-Dialkyl Thiophosphoramidates with Phosphorus Oxychloride - A Convenient Synthesis of Nitrogen Heterocyclic S-Alkyl Thiophosphoramidic Acid Derivatives
Tang, C.-C.
Lang, H.-F.
He, Z.-J.
Heteroatom Chemistry, 7 (03):
[3] The isomerization/chlorination of nitrogen heterocyclic O,O-dialkyl thiophosphoramidates with phosphorus oxychloride - A convenient synthesis of nitrogen heterocyclic S-alkyl thiophosphoramidic acid derivatives
Tang, CC
Lang, HF
He, ZJ
HETEROATOM CHEMISTRY, 1996, 7 (03) : 207 - 210
[4] The isomerization/chlorination of O,O-dialkyl N,N-dialkyl thiophosphoramidate with phosphorus oxychloride - A new method for synthesis of S-alkyl N,N-dialkyl thiophosphoramidic acid derivatives
Tang, CC
Wu, GP
He, SJ
He, ZJ
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1995, 101 (1-4): : 91 - 94
[5] The Isomerization/Chlorination of O,O-Diallyl Thiophosphoric (-nic) Acid Esters with Phosphorus Oxychloride─A New Convenient Method for Synthesis of S-Alkyl Thiophosphoric(-nic) Acid Derivatives
Zheng Jie HE
Ju Xiang LIU
Zheng Hong ZHOU
and Chu Chi TANG(State Key Laboratory of Elemento-Organic Chemistry
ChineseChemicalLetters, 1998, (10) : 903 - 905
[6] The isomerization/chlorination of O,O-diallyl thiophosphoric(-nic) acid esters with phosphorus oxychloride - A new convenient method for synthesis of S-alkyl thiophosphoric(-nic) acid derivatives
He, ZJ
Liu, JX
Zhou, ZH
Tang, CC
CHINESE CHEMICAL LETTERS, 1998, 9 (10) : 903 - 905
[7] A CONVENIENT SYNTHESIS OF S-ALKYL PHENYLTHIOPHOSPHONIC ACID DERIVATIVES
Chu Chi TANG Gui Ping WU Institute of Elemento-Organic Chemistry
ChineseChemicalLetters, 1992, (12) : 967 - 968
[8] The chlorination reaction of O-alkyl S-alkyl(aryl) thiophosphoric(-nic) acid derivatives with phosphorus oxychloride
He, ZJ
Chen, WB
Ma, FP
Zhou, ZH
Tang, CC
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1998, 142 : 49 - 55
[9] A CONVENIENT SYNTHESIS OF S-ALKYL O-ARYL THIOPHOSPHORIC ACID-DERIVATIVES
TANG, CC
WU, GP
ZHANG, GZ
SYNTHESIS-STUTTGART, 1991, (06): : 454 - 456
[10] The chlorination of O-alkyl S-alkyl(aryl) thiophosphoric(-nic) acids derivatives with phosphorus oxychloride -: A new method for synthesis of S-alkyl(aryl) thiophosphoro(-no)chloridates
He, ZJ
Chen, WB
Ma, FP
Zhou, ZH
Tang, CC
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1999, 20 (01): : 54 - 58

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