Energy transfer from O(D-1) to O-2

被引：17
|
作者：
Izod, T. P. J. [1 ]
Wayne, R. P. [1 ]
机构：
[1] Phys Chem Lab, Oxford OX1 3QZ, England
来源：
CHEMICAL PHYSICS LETTERS | 1969年 / 4卷 / 04期
关键词：
D O I：
10.1016/0009-2614(69)80103-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The efficiency of the energy transfer process O(D-1) + O-2((3)Sigma(-)(g)) -> O-2((1)Sigma(+)(g)) + O(P-3) has been assessed relative to the efficiency of quenching of O(D-1) O(D-1) + O-2((3)Sigma(-)(g)) -> O-2((3)Sigma(-)(g)) + O(P-3). Excited atomic oxygen was generated by the vacuum ultraviolet photolysis of oxygen, and O-2((1)Sigma(+)(g)) was detected in a time-resolved flow system by optical emission at lambda = 762nm. One O-2((1)Sigma(+)(g)) molecule is found to be formed for about 180 O(D-1) atoms deactivated: the relation of this result to the excitation efficiency obtained by other workers is discussed.
引用
收藏
页码：208 / 210
页数：3
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