FINITE SUPERCLUSTER MODEL OF VANADIUM-OXIDE CATALYSTS

被引：6
|
作者：
PETELENZ, P [1 ]
BROCLAWIK, E [1 ]
机构：
[1] POLISH ACAD SCI,INST CATALYSIS & SURFACE CHEM,PL-30239 KRAKOW,POLAND
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 68卷 / 02期
关键词：
D O I：
10.1016/0304-5102(91)80077-G
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A simple model approach is proposed to describe the penetration of an extra electron, transferred from a chemisorbed molecule, onto the surface of a vanadium oxide catalyst. The model provides conclusions regarding the probable penetration range. The necessary numerical parameters are estimated from the results of semiempirical SINDO calculations performed for small molecular clusters.
引用
收藏
页码：223 / 236
页数：14
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