SPONTANEOUS RADIATIVE PROPERTIES OF THE EXCITED ELECTRONIC STATES OF TIO

被引：15
|
作者：
SCHAMPS, J
SENNESAL, JM
CARETTE, P
机构：
[1] Laboratoire de Dynamique Moléculaire et Photonique, Unité de Recherche Associée au C.N.R.S. No. 779, Université des Sciences et Technologies de Lille
来源：
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 1992年 / 48卷 / 02期
关键词：
D O I：
10.1016/0022-4073(92)90084-H
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Ab initio electronic wavefunctions have been used to calculate and interpret absolute transition probabilities and oscillator strengths for all of the transitions involving the observed valence states of TiO. Spontaneous radiative lifetimes have been derived from the calculated probabilities and compared to related experimental data. The transitions are shown to be primarily atomically-forbidden transitions allowed in the molecule by orbital polarization.
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页码：147 / 152
页数：6
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