SYNTHESIS, STRUCTURE, AND PHOTOREACTION OF BIS(GERMANIMINES)

被引：30
|
作者：
ANDO, W
OHTAKI, T
KABE, Y
机构：
[1] Department of Chemistry, University of Tsukuba, Tsukuba
来源：
ORGANOMETALLICS | 1994年 / 13卷 / 02期
关键词：
D O I：
10.1021/om00014a013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of bis[bis(trimethylsilyl)methyl]-germylene (1) with N-(azidosilyl)germanimines 3a,b at room temperature gave bis(germanimines) 4a,b in quantitative yield whose structures have been confirmed by single-crystal X-ray diffraction. The photolysis of 4a gave the cyclic silanimine 6 as an unexpected product.
引用
收藏
页码：434 / 435
页数：2
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