ESTIMATION OF THE SHARMA CONSTANT AND THERMOACOUSTIC PROPERTIES OF VEGETABLE-OILS

被引:7
|
作者
SUBRAHMANYAM, MSR
VEDANAYAGAM, HS
VENKATACHARYULU, P
机构
[1] NAGARJUNA UNIV,DEPT PHYS,NAGARJUNA NAGAR 522510,ANDHRA PRADESH,INDIA
[2] PRAGATHI MAHA VIDYALAYA COLL,HYDERABAD 500007,ANDHRA PRADESH,INDIA
[3] INDIAN INST CHEM TECHNOL,HYDERABAD 500007,ANDHRA PRADESH,INDIA
关键词
DENSITY; HUGGINS PARAMETER; ISOCHORIC TEMPERATURE COEFFICIENT OF INTERNAL PRESSURE; ISOCHORIC TEMPERATURE COEFFICIENT OF VOLUME EXPANSION; PHYSICOCHEMICAL PROPERTIES; REDUCED COMPRESSIBILITY; REDUCED VOLUME; SHARMA CONSTANT; VEGETABLE OILS; VOLUME EXPANSIVITY;
D O I
10.1007/BF02540471
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The density and volume of four Indian edible vegetable oils, sunflower, rice bran, groundnut and coconut, and one Indian nonedible oil, castor oil, have been experimentally determined. The values obtained were used to estimate the volume expansivity alpha, hence the thermoacoustic parameters, such as the Sharma constant S-0, the isochoric temperature coefficient of internal pressure [dlnPi/dlnT](V), the isochoric temperature coefficient of volume expansion [dlna/dlnT]V-,V- reduced volume ($) over tilde V, reduced compressibility ($) over tilde beta and the Huggins parameter F. The results obtained show that the Sharma constant S-0 has the same characteristic value of 1.11 +/- 0.01 for the five oils, thus establishing the constancy of the Sharma parameter. All the other parameters are of the expected order of magnitude; however, in all cases there is a uniform deviation at 293 degrees K, which can be attributed to the behavior of density and volume at this temperature.
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页码:901 / 905
页数:5
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