HOMOLYTIC AND HETEROLYTIC CLEAVAGE ENERGIES FOR CARBON NITROGEN BONDS

被引:24
|
作者
ARNETT, EM
VENIMADHAVAN, S
AMARNATH, K
机构
[1] Department of Chemistry, Duke University, Durham
关键词
D O I
10.1021/ja00040a018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using calorimetric and electrochemical techniques described in previous reports, we have determined the heterolytic and homolytic bond energies at 25-degrees-C in sulfolane for the carbon-nitrogen bonds in the compounds produced by reactions of nine resonance-stabilized carbenium ions with nitranions formed by deprotonating the following nitrogen acids: succinimide, phthalimide, carbazole, and 3,6-dibromocarbazole.
引用
收藏
页码:5598 / 5602
页数:5
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