HOMOLYTIC AND HETEROLYTIC CLEAVAGE ENERGIES FOR CARBON NITROGEN BONDS

被引：24
|
作者：
ARNETT, EM
VENIMADHAVAN, S
AMARNATH, K
机构：
[1] Department of Chemistry, Duke University, Durham
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 14期
关键词：
D O I：
10.1021/ja00040a018
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Using calorimetric and electrochemical techniques described in previous reports, we have determined the heterolytic and homolytic bond energies at 25-degrees-C in sulfolane for the carbon-nitrogen bonds in the compounds produced by reactions of nine resonance-stabilized carbenium ions with nitranions formed by deprotonating the following nitrogen acids: succinimide, phthalimide, carbazole, and 3,6-dibromocarbazole.
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收藏
页码：5598 / 5602
页数：5
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