CRYSTAL-STRUCTURE OF AN INTERMEDIATE IN THE SYNTHESIS OF ARTEMISININ

被引：0

作者：

ZUKERMANSCHPECTOR, J ^{[1
]}

CONSTANTINO, MG ^{[1
]}

BELTRAME, M ^{[1
]}

机构：

[1] UNIV SAO PAULO,FAC FILOSOFIA CIENCIAS & LETRAS RIBEIRAO PRETO,DEPT QUIM,RIBEIRAO PRET,SP,BRAZIL

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1995年 / 25卷 / 07期

关键词：

ARTEMISININ; ISOPULEGOL; X-RAY DIFFRACTION;

D O I：

10.1007/BF01665279

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

C(14)H(22)O(3)r M(tau) = 238.33, P2(1)2(1)2(1), Z = 4, a = 6.892(2), b = 11.453(1), c = 17.159(5) Angstrom. [1R - [1 alpha(R*), 4 beta, 4a beta, 8a beta]] - alpha,4-Dimethyl-decahydro-7-oxo-1-naphtaleneacetic acid. The cyclohexane ring adopts a chair conformation and the cis-fused cyclohexanone ring is in a slightly distorted chair conformation. The molecular packing involves an hydrogen bond and C-H ... O contacts.

引用

页码：413 / 416

页数：4

共 50 条

[41] SYNTHESIS, CRYSTAL-STRUCTURE, AND STABILITY OF PYRUVOYLPENTACARBONYLMANGANESE(I)
CASEY, CP
BUNNELL, CA
CALABRESE, JC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (05) : 1166 - 1171
[42] METHYLBIS(DITHIOCARBAMATO)STIBANES - SYNTHESIS AND CRYSTAL-STRUCTURE
WIEBER, M
WIRTH, D
METTER, J
BURSCHKA, C
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 520 (01): : 65 - 70
[43] SYNTHESIS AND CRYSTAL-STRUCTURE OF TETRACARBONYL(TRIPHENYLSTIBINE)-RUTHENIUM
FORBES, EJ
JONES, DL
PAXTON, K
HAMOR, TA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (05): : 879 - 882
[44] SYNTHESIS AND CRYSTAL-STRUCTURE OF ETHYLENEDIAMMONIUM DIHYDROGEN DIPHOSPHATE
AVERBUCHPOUCHOT, MT
DURIF, A
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1993, 316 (02): : 187 - 192
[45] SYNTHESIS AND CRYSTAL-STRUCTURE OF A MONOCARBENE COMPLEX OF COPPER
RAUBENHEIMER, HG
CRONJE, S
VANROOYEN, PH
OLIVIER, PJ
TOERIEN, JG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (06): : 672 - 673
[46] SYNTHESIS AND CRYSTAL-STRUCTURE OF CESIUM DIAQUATETRAFLUOROMANGANATE(III)
BUKOVEC, P
KAUCIC, V
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09): : 945 - 947
[47] SYNTHESIS, PROPERTIES AND CRYSTAL-STRUCTURE OF METHYLGALLIUM DIACETATE
HAUSEN, HD
SILLE, K
WEIDLEIN, J
SCHWARZ, W
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (02) : 411 - 419
[48] SYNTHESIS AND CRYSTAL-STRUCTURE OF NEW POTASSIUM ALUMINATE
BON, A
GLEITZER, C
COURTOIS, A
PROTAS, J
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1974, 278 (11): : 785 - 788
[49] SYNTHESIS AND CRYSTAL-STRUCTURE OF TETRAKIS(PENTAFLUOROPHENYLAMINO)SILANE
JANSEN, M
RINGS, S
BALDUS, HP
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 610 (04): : 99 - 102
[50] SYNTHESIS AND CRYSTAL-STRUCTURE OF SRBISE3
COOK, R
SCHAFER, H
REVUE DE CHIMIE MINERALE, 1982, 19 (01): : 19 - 27

← 1 2 3 4 5 →