DECOMPOSITION OF METHANOL ON METHANOL SYNTHESIS CATALYSTS CONTAINING COPPER

被引：0

作者：

SHLEGEL, L ^{[1
]}

GUTSHIK, D ^{[1
]}

ROZOVSKII, AY ^{[1
]}

机构：

[1] AV TOPCHIEV PETROCHEM SYNTH INST,MOSCOW,USSR

来源：

KINETICS AND CATALYSIS | 1990年 / 31卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have investigated the dynamics of the conversion of methanol on the catalyst CuO-ZnO-Al2O3 in a static system. On a freshly reduced catalyst the first products of the conversion of methanol are CO2 and H2, formed with the participation of firmly bound chemisorbed water (zH2O + CH3OH --> z + CO2 + 3H2) and also methyl formate. When the chemisorbed water is used up, the main reaction remains the formation of methyl formate (2CH3OH --> CH3OCHO + 2H2). It is shown that CO is formed in secondary reactions by the decomposition of methyl formate.

引用

页码：880 / 882

页数：3

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