OXALATE FORMATION IN ELECTROCHEMICAL CO2 REDUCTION CATALYZED BY RHODIUM-SULFUR CLUSTER

被引：30

作者：

KUSHI, Y ^{[1
]}

NAGAO, H ^{[1
]}

NISHIOKA, T ^{[1
]}

ISOBE, K ^{[1
]}

TANAKA, K ^{[1
]}

机构：

[1] GRAD INST ADV SCI, INST MOLEC SCI, DEPT STRUCT SCI, OKAZAKI, AICHI 444, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical reduction of CO2 catalyzed by a triangular rhodium complex [(RhCp*)(3)(mu(3)-S)(2)](2+) selectively produced formate and oxalate in the presence of Bu(4)NBF(4) and LiBF4, respectively, under the controlled potential electrolysis at -1.50 V (vs. SCE) in CO2-saturated CH3CN. A solution IR spectrum evidenced the adduct formation between [(RhCp*)3(mu(3)-S)(2)](0) and CO2 as the possible precursor for the oxalate formation.

引用

页码：2175 / 2178

页数：4

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