INTRAMOLECULARLY STABILIZED GALLACYCLOHEXANES AND INDACYCLOHEXANES, GALLACYCLOPENTANES, INDACYCLOPENTANES AND GALLACYCLOPENTENES, INDACYCLOPENTENES - X-RAY STRUCTURAL-ANALYSIS OF (CH2)(5)GA(CH2)(3)NME(2), (CH2)(5)GACH(2)CHCH(3)CH(2)NME(2) AND (C6F(5))(2)IN(CH2)(3)NME(2)

被引：21

作者：

SCHUMANN, H

JUST, O

SEUSS, TD

GORLITZ, FH

WEIMANN, R

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 466卷 / 1-2期

关键词：

GALLIUM; INDIUM; CYCLOHEXANE; CYCLOPENTANE; CYCLOPENTENE; ZIRCONIUM;

D O I：

10.1016/0022-328X(94)88023-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The intramolecularly stabilized metallacyclic organogallium and organoindium compounds (CH2)(n)M(CH2)(3)NR(2) (2, 3, 4, 7) and (CH2)(n)GaCH(2)CHMeCH(2)NMe(2) (5, 6) have been synthesized from GaCl3 or InCl3 and (3-dimethylamino)propyl lithium, (3-diethylamino)propyl lithium or (3-dimethylamino)-2-methylpropyl lithium, and BrMg(CH2)(n)MgBr (n = 4, 5). (C6F5)(2)InBr reacts with (3-dimethylamino)propyl lithium yielding (C6F5)(2)In(CH2)(3)NMe(2) (8), and CH(2)CMe=CMeCH(2)Ga(CH2)(3)NMe(2) (10) was made from (C5H5)(2)ZrCH(2)CMe=CMeCH(2) and Cl2Ga(CH2)(3)NMe(2). The H-1, C-13 NMR and mass spectra of the new compounds, as well as the X-ray crystal structure analyses of 4, 6, and 8 are discussed.

引用

页码：5 / 14

页数：10

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