FLUOROPLATINATES(IV) OF THE LANTHANIDES LNF[PTF6] (LN = PR, SM, GD, TB, DY, HO, ER)

被引：8

作者：

SCHROTTER, F ^{[1
]}

MULLER, BG ^{[1
]}

机构：

[1] JUSTUS LIEBIG UNIV,INST ANORGAN & ANALYT CHEM I,HEINRICH BUFF RING 58,D-35392 GIESSEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 08期

关键词：

FLUOROPLATINATES(IV); PREPARATION; SINGLE CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19936190819

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the first time fluorides LnF[PtF6] (Ln = Pr, Sm, Gd, Th, Dy, Ho, Er), all yellow have been obtained. From single crystal data they crystallize monoclinic, space group P2(1)/n-C2h5 (No. 14), Z = 4, Pr: a = 1125.77(19) pm, b = 559.04(7) pm, c = 910.27(17) pm, beta 107.29(1)-degrees; Sm: a = 1114.63(31) pm, b = 552.70(12) pm, c = 898.02(20) pm, beta = 107.24(2)-degrees; Gd: a = 1112.12(15) pm, b = 551.22(7) pm, c = 891.99(11) pm, beta = 107.09(1)-degrees; Th (Powder data): a = 1108.88(20) pm, b = 552.71(9) pm, c = 889.56(16) pm, beta = 107.30(1)-degrees; Dy: a = 1100.28(23) pm, b = 547.77(8) pm, c = 882.41(13) pm, beta = 107.32(1); Ho: a = 1099.11(16) pm, b = 546.16(7) pm, c = 879.45(15) pm, beta = 107.34(1)-degrees; Er: a = 1095.10(16) pm, b = 544.82(10) pm, c = 874.85(14) pm, 8 = 107.37(1)-degrees.

引用

页码：1431 / 1440

页数：10

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