MOLECULAR CLUSTERS AND CORRELATIONS IN LIQUID METHANOL AT ROOM-TEMPERATURE

被引：134

作者：

SARKAR, S

JOARDER, RN

机构：

[1] Department of Physics, Jadavpur University

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 03期

关键词：

D O I：

10.1063/1.465266

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The analysis of x-ray diffraction data of liquid methanol at room temperature reveals a distinct possibility of the presence of hexamer molecular clusters due to intermolecular hydrogen bonding. On the assumption of hexamer domination in the structure, the center structure is derived, which in turn reproduces closely the available data on neutron diffraction and computer simulation for this system. The center-center correlations show special features of bonded structure.

引用

页码：2032 / 2039

页数：8

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