THE MICROWAVE-SPECTRUM OF BRNC O-18 AND THE STRUCTURE OF BROMINE ISOCYANATE

被引：8
|
作者：
HENSEL, KD [1 ]
LAM, ME [1 ]
GERRY, MCL [1 ]
WILLNER, H [1 ]
机构：
[1] UNIV HANOVER,INST ANORGAN CHEM,W-3000 HANNOVER,GERMANY
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1992年 / 151卷 / 01期
关键词：
D O I：
10.1016/0022-2852(92)90014-F
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The microwave spectrum of BrNC18O has been measured in the frequency region 23-52 GHz. Because the spectrum is that of a prolate near-symmetric rotor with strong a-type and weak b-type transitions, perturbations in the quadrupole hyperfine patterns of Br were used to improve the precision of A0. The geometry of the molecule has been determined; in particular, the NCO chain has been found to have a bend of ∼8° away from Br. © 1992.
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页码：184 / 196
页数：13
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