Methodical Factors in Coulometric Determination of the Sum of Uranium and Plutonium Weight Fractions in MOX Fuel

被引：3
|
作者：
Momotov, V. N. [1 ]
Erin, E. A. [1 ]
Chistyakov, V. M. [1 ]
机构：
[1] Res Inst Atom Reactors, Dimitrovgrad 10, Ulyanovsk Oblast 433510, Russia
来源：
RADIOCHEMISTRY | 2014年 / 56卷 / 03期
关键词：
uranium; plutonium; zinc amalgam; coulometry; spectrophotometry; oxidation; reduction; methodical factors;
D O I：
10.1134/S1066362214030138
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The influence exerted on the accuracy of coulometric titration by the composition of the supporting electrolyte solution in the titration step, by the way of stirring of the supporting electrolyte solution, by the weight of the aliquot of the solution being titrated, by the weight of the substance being titrated in the aliquot, by the kind of reductant, and by the solution compositions in the steps of oxidation and reduction of U-Pu mixtures was studied by spectrophotometry and coulometry. The optimum conditions for performing the analysis were found.
引用
收藏
页码：302 / 307
页数：6
相关论文
共 35 条
  • [31] NITROGEN DETERMINATION IN MIXED URANIUM-PLUTONIUM FUEL AFTER N-14(ALPHA, P-GAMMA) REACTION
    MELENTEV, VI
    OVECHKIN, VV
    SOVIET ATOMIC ENERGY, 1980, 48 (03): : 202 - 204
  • [32] DETERMINATION OF OXIDATION-STATES OF URANIUM AND PLUTONIUM IN COOLING SOLUTION OF SPENT FUEL-ELEMENT ASSEMBLIES FROM NPP A-1
    PRAZSKY, M
    ADAMEK, A
    BINKA, J
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1989, 129 (02): : 289 - 294
  • [33] DETERMINATION OF ISOTOPIC COMPOSITION AND CONCENTRATION OF URANIUM, PLUTONIUM AND NEODYMIUM BY MASS-SPECTROMETRIC ISOTOPE-DILUTION IN THE IRRADIATED FUEL OF THE CZECHOSLOVAK ATOMIC POWER-STATION A-1
    SUS, F
    KRTIL, J
    BULOVIC, V
    KLOSOVA, E
    MAKSIMOVIC, Z
    JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1979, 51 (01): : 143 - 151
  • [34] Poly(3,4-ethylenedioxythiophene)-Poly(styrenesulfonate)-Coated Glassy-Carbon Electrode for Simultaneous Voltammetric Determination of Uranium and Plutonium in Fast-Breeder-Test Reactor Fuel
    Agarwal, Rahul
    Sharma, Manoj K.
    Jayachandran, Kavitha
    Gamare, Jayashree S.
    Noronha, Donald M.
    Lohithakshan, Kaiprath V.
    ANALYTICAL CHEMISTRY, 2018, 90 (17) : 10187 - 10195
  • [35] APPLICATION OF ISOTOPE-DILUTION METHOD FOR MASS-SPECTROMETRIC AND ALPHA-SPECTROMETRIC DETERMINATION OF BURN-UP AND URANIUM, PLUTONIUM AND TRANSPLUTONIUM ELEMENT CONTENT IN VVER-440 SPENT FUEL
    MAKAROVA, TP
    PREOBRAZHENSKAYA, LD
    LOVTSYUS, AV
    FRIDKIN, AM
    STEPANOV, AV
    LIPOVSKII, AA
    BELYAEV, BN
    JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1983, 80 (1-2): : 173 - 182
1234