CHEMOENZYMATIC SYNTHESIS OF DISCOTIC LIQUID-CRYSTALS

被引:25
|
作者
VILL, V
SAUERBREI, B
FISCHER, H
THIEM, J
机构
[1] UNIV HAMBURG,INST ORGAN CHEM,MARTIN LUTHER KING PL 6,W-2000 HAMBURG 13,GERMANY
[2] MARTIN LUTHER UNIV,INST PHYS CHEM,O-4020 HALLE,GERMANY
关键词
D O I
10.1080/02678299208030698
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Acylations at the 6-position of alkyl glycosides were obtained using the esterification potential of lipases. Thus, sugars with two alkyl chains result showing columnar discotic phases. The correlation between the configuration of the sugar moieties and the different clearing points can be understood on the basis of simple stereochemical assumptions.
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页码:949 / 952
页数:4
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