CRYSTAL-STRUCTURE OF MGCL2(1,2-DIMETHOXYETHANE)2

被引：0

作者：

NEUMULLER, B ^{[1
]}

STIEGLITZ, G ^{[1
]}

DEHNICKE, K ^{[1
]}

机构：

[1] UNIV MARBURG, FACHBEREICH CHEM, HANS MEERWEIN STR, D-35032 MARBURG, GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1993年 / 48卷 / 08期

关键词：

MAGNESIUM CHLORIDE-DME SOLVATE; CRYSTAL STRUCTURE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MgCl2(DME)2 has been prepared by reaction of MgCl2 with excess dimethoxyethane (DME) in n-pentane solution as white crystals, which are soluble in organic solvents. The crystal structure was determined by X-ray methods. Space group P2(1)/c, Z = 4,2512 observed unique reflections, R = 0.050. Lattice dimensions at -70-degrees-C: a = 1338.9(1), b = 845.1(1), c = 1315.3(2) pm, beta = 112.69(1)degrees. The magnesium atom is in a distorted octahedral coordination by the two chlorine atoms in cis-positions and by the four oxygen atoms of two chelating 1,2-dimethoxyethane molecules.

引用

页码：1151 / 1153

页数：3

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