PREPARATION OF CARBON MOLECULAR-SIEVES BY PROPYLENE PYROLYSIS OVER NICKEL-IMPREGNATED ACTIVATED CARBONS

被引：11

作者：

VERMA, SK ^{[1
]}

WALKER, PL ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT MAT SCI & ENGN,UNIV PK,PA 16802

来源：

CARBON | 1993年 / 31卷 / 07期

关键词：

MOLECULAR SIEVES; NI; PROPYLENE; O-2; AR; CARBON;

D O I：

10.1016/0008-6223(93)90073-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Exploratory runs have shown it to be possible to produce a sieve for the separation of O-2 from Ar by depositing carbon from propylene in or over an activated carbon (AC) previously impregnated with Ni. It is thought that preferential cracking of propylene at the Ni sites within the pores of the AC particles and/or at the particle exterior surface introduces apertures of size 0.54-0.57 nm-the size required for this separation.

引用

页码：1203 / 1207

页数：5

共 39 条

[11] Chlorine Adsorption of Activated Carbons, Carbon Molecular Sieves and Carbon Nanotubes
Xue, Jian-Wei
Wen, Xiao-Guang
Zhao, Hui-Ling
Lv, Zhi-Ping
Li, Fu-Xiang
ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (12) : 5481 - 5484
[12] Nickel-impregnated zirconium-doped mesoporous molecular sieves as catalysts for the hydrogenation and ring-opening of tetralin
Rodríguez-Castellón, E
Díaz, L
Braos-García, P
Mérida-Robles, J
Maireles-Torres, P
Jiménez-López, A
Vaccari, A
APPLIED CATALYSIS A-GENERAL, 2003, 240 (1-2) : 83 - 94
[13] PROPANE CARBON-DIOXIDE AND PROPYLENE CARBON-DIOXIDE MIXTURE ADSORPTION IN 5A MOLECULAR-SIEVES
CROSSER, OK
HONG, BV
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1980, 25 (04): : 339 - 340
[14] CO2 as an adsorptive to characterize carbon molecular sieves and activated carbons
Cazorla-Amoros, D
Alcaniz-Monge, J
de la Casa-Lillo, MA
Linares-Solano, A
LANGMUIR, 1998, 14 (16) : 4589 - 4596
[15] PROPYLENE OLIGOMERIZATION OVER MOLECULAR-SIEVES .1. ZEOLITE EFFECTS ON REACTIVITY AND LIQUID PRODUCT SELECTIVITIES
OCCELLI, ML
HSU, JT
GALYA, LG
JOURNAL OF MOLECULAR CATALYSIS, 1985, 32 (03): : 377 - 390
[16] CHARACTERIZATION OF CARBON MOLECULAR-SIEVES AND ACTIVATED-CHARCOAL FOR USE IN AIRBORNE CONTAMINANT SAMPLING
BETZ, WR
MAROLDO, SG
WACHOB, GD
FIRTH, MC
AMERICAN INDUSTRIAL HYGIENE ASSOCIATION JOURNAL, 1989, 50 (04): : 181 - 187
[17] Synthesis of carbon molecular sieves by benzene pyrolysis over microporous carbon materials
David, E
Talaie, A
Stanciu, V
Nicolae, AC
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2004, 157 : 290 - 296
[18] A SYSTEMATIC INVESTIGATION OF THE PREPARATION AND PROPERTIES OF COMPOSITE CARBON MOLECULAR-SIEVES CONTAINING INORGANIC OXIDES
FOLEY, HC
LAFYATIS, D
SINGH, R
GARRISON, D
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 172 - IAEC
[19] Adsorption properties of carbon molecular sieves prepared from an activated carbon by pitch pyrolysis
Lozano-Castello, D
Alcaniz-Monge, J
Cazorla-Amorós, D
Linares-Solano, A
Zhu, W
Kapteijn, F
Moulijn, JA
CARBON, 2005, 43 (08) : 1643 - 1651
[20] MASS-TRANSFER COEFFICIENTS IN CRYOSORPTION OF HYDROGEN ISOTOPES ON MOLECULAR-SIEVES OR ACTIVATED CARBON AT 77 K
NISHIKAWA, M
UETAKE, M
TANAKA, KI
SHIRAISHI, T
FUSION TECHNOLOGY, 1995, 28 (03): : 717 - 722

← 1 2 3 4 →