REGIOSELECTIVE DEACYLATION OF POLYACETOXY ARYL-METHYL KETONES BY LIPASES IN ORGANIC-SOLVENTS

被引:32
|
作者
PARMAR, VS
PRASAD, AK
SHARMA, NK
SINGH, SK
PATI, HN
GUPTA, S
机构
[1] Department of Chemistry, University of Delhi, Delhi
关键词
D O I
10.1016/S0040-4020(01)88239-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Lipases from porcine pancreas and Candida cylindracea, suspended in organic solvents have been used to study regioselective deacylation of polyacetoxy acetophenones. It has been observed that the hydrolysis of acetate groups at positions other than ortho predominates.
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页码:6495 / 6498
页数:4
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