KINETICS OF THE REACTION OF 2,6-DI-TERT-BUTYLPHENOL WITH METHYL ACRYLATE IN THE PRESENCE OF POTASSIUM 2,6-DI-TERT-BUTYLPHENOLATE AND THE EFFECT OF PROTON DONOR COMPONENTS ON THE REACTION-MECHANISM

被引：0
|
作者：
VOLODKIN, AA
ZAIKOV, GE
DEEV, AS
机构：
[1] Institute of Chemical Physics, the USSR Academy of Sciences, Moscow
来源：
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS | 1992年 / 16卷 / 1-4期
关键词：
2,6-DI-TERT-BUTYLPHENOL; METHYL ACRYLATE REACTION MECHANISM;
D O I：
10.1080/00914039208035414
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetic scheme of the reaction of 2,6-di-tert-butylphenol (ArOH) with methyl acrylate (MA) in the presence of potassium 2,6-di-tert-butylphenolate (ArOK) is proposed and elementary constants are calculated for the catalytic steps and the influence of proton donor components ArOH, H20 and CH3OH on kinetic regularities is studied. The kinetic scheme contains 30 components and involves 62 rate constants of elementary steps which were computed by the mathematical simulation method of process kinetics using a computer. The comparison was carried out for the computed and experimental data relating to the consumption rate dependence of ArOH on ArOK concentration and the concentration of proton donor components. © 1992, Taylor & Francis Group, LLC. All rights reserved.
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页码：121 / 130
页数：10
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