A STABLE COMPOUND WITH A FORMAL TIN CARBON DOUBLE-BOND - THE BIS(2,4,6-TRIISOPROPYLPHENYL)(FLUORENYLIDENE)STANNENE

被引：53

作者：

ANSELME, G ^{[1
]}

RANAIVONJATOVO, H ^{[1
]}

ESCUDIE, J ^{[1
]}

COURET, C ^{[1
]}

SATGE, J ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,CHIM ORGANOMINERAUX LAB,URA 477,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 08期

关键词：

D O I：

10.1021/om00044a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(2,4,6-triisopropylphenyl)(fluorenylidene)stannene-diethyl ether (1a), a new stable compound with a formal tin-carbon double bond, has been synthesized by dehydrofluorination of the corresponding fluoro-stannane with tert-butyllithium; it has been characterized by NMR (delta(Sn-119) + 288 ppm, delta(C-13) + 133.85 ppm) and UV spectroscopy (lambda(max) 542 nm) and by electrophilic addition reactions to the tin-carbon unsaturation,

引用

页码：2748 / 2750

页数：3

共 50 条

[41] CRYSTAL AND MOLECULAR-STRUCTURE OF BINUCLEAR CO2(MU-PPH2)2(CO)2(PET2PH)2, A PHOSPHIDO-BRIDGED COMPOUND WITH A FORMAL COBALT COBALT DOUBLE-BOND
HARLEY, AD
WHITTLE, RR
GEOFFROY, GL
ORGANOMETALLICS, 1983, 2 (01) : 60 - 63
[42] THE HEAT-CAPACITY OF (CH2=CHCH2NH3)2CDCL4 - THE INFLUENCE OF THE CARBON-CARBON DOUBLE-BOND ON THE STRUCTURAL PHASE-TRANSITIONS
WHITE, MA
STAVELEY, LAK
JOURNAL OF CHEMICAL THERMODYNAMICS, 1982, 14 (09): : 859 - 864
[43] Carbon-Carbon Double-Bond Isomerization and Diels-Alder Reaction of Dimethyl 5-Methylene-4-isopropylidene-2-cycloheptene-1,1-dicarboxylate with Dienophiles
Lu, Ping
Kuang, Jinqiang
Ma, Shengming
SYNLETT, 2010, (02) : 227 - 230
[44] Crystal structure of bis(2-(2,6-diisopropyl-phenylamino)-6-(2,4,6-triisopropylphenyl)-pyridinium) hexachloro-titanate(IV) toluene solvate, (C32H45N2)2[TiCl6] •C7H8
Dietel, Anna M.
Irrgang, Torsten
Glatz, Germund
Karthikeyan, Sangeetha
Kempe, Rhett
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (03): : 284 - 286
[45] The Synthesis of Energetic Compound on 4,4′-((2,4,6-trinitro-1,3-phenylene)bis(oxy)) bis(1,3-dinitrobenzene)(ZXC-5): Thermally Stable Explosive with Outstanding Properties
Zhang, XingCheng
Xiong, HuaLin
Yang, HongWei
Cheng, GuangBin
PROPELLANTS EXPLOSIVES PYROTECHNICS, 2017, 42 (10) : 1203 - 1207
[46] CARBON-CARBON DOUBLE-BOND CLEAVAGE IN REACTIONS OF DIPHENYLCYCLOPROPENONE WITH PLATINUM(0) COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF MU-2-OXO-1,3-DIPHENYLPROPANEDIYLIDENE-BIS[BIS(T-BUTYL ISOCYANIDE)PLATINUM]
CARROLL, WE
GREEN, M
HOWARD, JAK
PFEFFER, M
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (11): : 1472 - 1478
[47] 2-(2,4,6-TRI-TERT-BUTYLPHENYL)-1-ARSAETHYNE - THE 1ST COMPOUND CONTAINING AN ARSENIC-CARBON TRIPLE BOND
MARKL, G
SEJPKA, H
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (03): : 264 - 264
[48] CONVERSION OF AN ELECTRON-RICH TRIPLE BOND TO A DOUBLE-BOND BY OXIDATIVE ADDITION OF DIPHENYL DISELENIDE TO RE2CL4(MU-BIS(DIPHENYLPHOSPHINO)METHANE)2 - PREPARATION AND CHARACTERIZATION OF RE2CL4(MU-SEPH)2(MU-BIS(DIPHENYLPHOSPHINO)METHANE)2
COTTON, FA
DUNBAR, KR
INORGANIC CHEMISTRY, 1987, 26 (08) : 1305 - 1309
[49] PHOTOCHEMICAL REACTIVITY OF KETO IMINO ETHERS .6. TYPE-1 REARRANGEMENT AND (2 + 2) PHOTOCYCLOADDITION TO CARBON-NITROGEN DOUBLE-BOND OF 2-OXAZOLIN-4-ONES
RODEHORST, RM
KOCH, TH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (25) : 7298 - 7304
[50] PREPARATION, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURE OF RU2H6N2-(PPH3)4, A COMPOUND CONTAINING 4 BRIDGING HYDRIDES AND A RUTHENIUM RUTHENIUM DOUBLE-BOND
CHAUDRET, B
DEVILLERS, J
POILBLANC, R
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (11) : 641 - 643

← 1 2 3 4 5 →