LAYER CHARGE PROPERTIES OF SMECTITES AND VERMICULITES - TETRAHEDRAL VS OCTAHEDRAL

被引：38
|
作者：
MALLA, PB [1 ]
DOUGLAS, LA [1 ]
机构：
[1] RUTGERS STATE UNIV,DEPT SOILS & CROPS,NEW BRUNSWICK,NJ 08903
来源：
SOIL SCIENCE SOCIETY OF AMERICA JOURNAL | 1987年 / 51卷 / 05期
关键词：
GEOLOGY - Stratigraphy - ION EXCHANGE - MINERALOGY - Silicates;
D O I：
10.2136/sssaj1987.03615995005100050048x
中图分类号：
S15 [土壤学];
学科分类号：
0903 ; 090301 ;
摘要：
Total layer charge and charge of octahedral sheets of 2:1 soil clays were estimated by combining alkylammonium ion exchange technique and the Hofmann and Klemen effect. The estimation of charge before and after Hofmann and Klemen effect (Li-saturation and heat treatment) gave the total layer and tetrahedral charge, respectively. The difference of total and tetrahedral charge provided the charge contribution of octahedral sheets, assuming that a complete neutralization of octahedral charge was achieved by Li** plus migration during the heat treatment. As much as 50% of the charge was found to be located in the octahedral sheets in soil smectics and soil vermiculites.
引用
收藏
页码：1362 / 1366
页数：5
相关论文
共 50 条
  • [21] THE LUMINESCENCE PROPERTIES OF OCTAHEDRAL AND TETRAHEDRAL MOLYBDATE COMPLEXES
    WIEGEL, M
    BLASSE, G
    JOURNAL OF SOLID STATE CHEMISTRY, 1992, 99 (02) : 388 - 394
  • [22] Thermal study of polypyrrole complexes with vermiculites of different layer charge
    Veronica Ramírez-Valle
    A. Lerf
    F. E. Wagner
    J. Poyato
    J. L. Pérez-Rodríguez
    Journal of Thermal Analysis and Calorimetry, 2008, 92 : 43 - 51
  • [23] Fe3+/Al3+ partitioning between tetrahedral and octahedral sites in dioctahedral smectites
    Decarreau, A.
    Petit, S.
    CLAY MINERALS, 2014, 49 (05) : 657 - 665
  • [24] Effect of layer charge on fixation of cesium ions in smectites
    Onodera, Y
    Iwasaki, T
    Ebina, T
    Hayashi, H
    Torii, K
    Chatterjee, A
    Mimura, H
    JOURNAL OF CONTAMINANT HYDROLOGY, 1998, 35 (1-3) : 131 - 140
  • [25] LAYER CHARGE OF SMECTITES IN AN ARGIALBOLL-ARGIAQUOLL SEQUENCE
    LAIRD, DA
    FENTON, TE
    SCOTT, AD
    SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 1988, 52 (02) : 463 - 467
  • [26] Traditional and novel methods for estimating the layer charge of smectites
    Czimerova, A.
    Bujdak, J.
    Dohrmann, R.
    APPLIED CLAY SCIENCE, 2006, 34 (1-4) : 2 - 13
  • [27] Layer charge estimation of smectites using infrared spectroscopy
    Petit, S
    Righi, D
    Madejová, J
    Decarreau, A
    CLAY MINERALS, 1998, 33 (04) : 579 - 591
  • [28] The concept of layer charge of smectites and its implications for important smectite-water properties
    Christidis, George E.
    LAYERED MINERAL STRUCTURES AND THEIR APPLICATION IN ADVANCED TECHNOLOGIES, 2011, 11 : 237 - 258
  • [29] Thermal study of polypyrrole complexes with vermiculites of different layer charge
    Ramirez-Valle, Veronica
    Lerf, A.
    Wagner, F. E.
    Poyato, J.
    Perez-Rodriguez, J. L.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 92 (01) : 43 - 51
  • [30] Interaction of octahedral Mg(II) and tetrahedral Al(III) substitutions in aluminium-rich dioctahedral smectites
    Lavikainen, Lasse P.
    Hirvi, Janne T.
    Kasa, Seppo
    Pakkanen, Tapani A.
    THEORETICAL CHEMISTRY ACCOUNTS, 2016, 135
12345