ELECTRON DONOR-ACCEPTOR COMPOUNDS .48. ELECTRON DONOR-ACCEPTOR [3.3]METACYCLOPHANES - CHARGE-TRANSFER ABSORPTION OF SYN-ISOMERS AND ANTI-ISOMERS

被引:4
|
作者
STAAB, HA
DOHLING, A
KRIEGER, C
机构
[1] Abteilung Organische Chemie Max-Planck-Institut für medizinische Forschung Jahnstrße 29
关键词
D O I
10.1016/S0040-4039(00)79684-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
As electron donor-acceptor [3.3]metacyclophanes with dicyanoquinomethane as acceptor unit in different sterical arrangements the syn- anti isomers 3 and 4 were synthesized. Charge-transfer interactions are discussed with reference to the isomerisation of 4 to 3 and to the absorption spectra.
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页码:2215 / 2218
页数:4
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