CHEMOSELECTIVE OXIDATIONS IN WATER OF FUNCTIONAL-GROUPS

被引：16

作者：

FRINGUELLI, F ^{[1
]}

PELLEGRINO, R ^{[1
]}

PIERMATTI, O ^{[1
]}

PIZZO, F ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,I-06100 PERUGIA,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 18期

关键词：

D O I：

10.1080/00397919408010580

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The organic functional groups, formyl, cyano, hydroxymethyl and methylsulfenyl, are oxidized with high yields in water only by using TBHP and controlling the pH of the reaction medium. In the presence of (CTA)(2)SO4, the oxidation of the easily oxidizable sulfide group is prevented and a highly chemoselective process is obtained. The role of the surfactant is discussed.

引用

页码：2665 / 2673

页数：9

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