DIRECT OBSERVATION OF PUSH EFFECT ON THE HETEROLYTIC O-O BOND-CLEAVAGE REACTION OF ACYLPEROXO-IRON(III) PORPHYRIN ADDUCTS

被引：14

作者：

YAMAGUCHI, K ^{[1
]}

WATANABE, Y ^{[1
]}

MORISHIMA, I ^{[1
]}

机构：

[1] KYOTO UNIV, GRAD SCH ENGN, DIV MOLEC ENGN, KYOTO 606, JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 23期

关键词：

D O I：

10.1039/c39920001709

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the first direct observation of the push effect of the sixth ligand on the heterolytic O-O bond cleavage step of acylperoxo-iron(III) porphyrin complexes to the corresponding oxo-ferryl porphyrin pi-cation radicals by utilizing a series of imidazole derivatives.

引用

页码：1709 / 1710

页数：2