DIRECT OBSERVATION OF PUSH EFFECT ON THE HETEROLYTIC O-O BOND-CLEAVAGE REACTION OF ACYLPEROXO-IRON(III) PORPHYRIN ADDUCTS

被引：14
|
作者：
YAMAGUCHI, K [1 ]
WATANABE, Y [1 ]
MORISHIMA, I [1 ]
机构：
[1] KYOTO UNIV, GRAD SCH ENGN, DIV MOLEC ENGN, KYOTO 606, JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 23期
关键词：
D O I：
10.1039/c39920001709
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the first direct observation of the push effect of the sixth ligand on the heterolytic O-O bond cleavage step of acylperoxo-iron(III) porphyrin complexes to the corresponding oxo-ferryl porphyrin pi-cation radicals by utilizing a series of imidazole derivatives.
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收藏
页码：1709 / 1710
页数：2
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