REACTIONS OF TRIHALODITHIATRIAZINES AND TRIFLUOROTRIAZINE WITH HALOGEN-LEWIS-ACIDS

被引:7
|
作者
CHEN, SJ [1 ]
BEHRENS, U [1 ]
OLBRICH, F [1 ]
MEWS, R [1 ]
机构
[1] UNIV BREMEN,INST ANORGAN & PHYS CHEM,LEOBENER STR NW2,POSTFACH 330440,D-28334 BREMEN,GERMANY
来源
关键词
TRIHALODITHIATRIAZINES; TRIHALOTRIAZINES; SALT-FORMATION; ADDUCT-FORMATION; X-RAY STRUCTURES;
D O I
10.1002/zaac.19936191017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
From the reaction of (XCN)(XSN)2 and MX5 (X = Cl, M = Sb; X = F, M = As) the corresponding salts [(XCN)(XSN)(SN)]+MX6- (2, 4) are obtained. (FCN)3 adds AsF5 to the nitrogen-bonded adduct (FCN)3 . AsF5 (6). The X-ray-structure of 6 is reported.
引用
收藏
页码:1725 / 1728
页数:4
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