RING TRANSFORMATIONS OF HETEROCYCLIC-COMPOUNDS .6. 3-NITROBENZONITRILES FROM 2,4,6-TRIARYLPYRYLIUM SALTS AND NITROACETONITRILE

被引：0

作者：

ZIMMERMANN, T ^{[1
]}

PINK, M ^{[1
]}

机构：

[1] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

来源：

LIEBIGS ANNALEN DER CHEMIE | 1993年 / 10期

关键词：

NITRILES; NITRO COMPOUNDS; BENZONITRILES; 3-NITRO; PYRYLIUM SALTS; NITROACETONITRILE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,4,6-Triarylpyrylium salts 1 react with nitroacetonitrile in the presence of sodium acetate, triethylamine, triethylamine/acetic acid or piperidine acetate to give 3-nitrobenzonitriles 2. In the course of this 2,6-[C5 + C] pyrylium ring transformation a nitro group is shifted to C-3 of the benzene ring formed. Structural elucidation of the reaction products 2 is based on an X-ray structure determination of the methoxyphenyl derivative 2c.

引用

页码：1145 / 1147

页数：3

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