SYNTHESES AND STRUCTURES OF FUNCTIONAL SUBSTITUTED FERROCENES

被引：10
|
作者：
GRUNHAGEN, A [1 ]
PIEPER, U [1 ]
KOTTKE, T [1 ]
ROESKY, HW [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 04期
关键词：
N; O-BIS(TRIMETHYLSILYL)FERROCENYLIMIDATE; E; Z-(FERROCENYL-TRIMETHYLSILOXYMETHYLIDEN)TRIMETHYLSILYLPHOSPHANE;
D O I：
10.1002/zaac.19946200422
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Substituted ferrocenes have been prepared using carbonic acid chloride of ferrocene. New pathways have been found reacting the acid chloride with sodium hexamethyldisilazane and tris(trimethylsilyl)phosphane, respectively. The compounds FecC(OSiMe3)N(SiMe3) (Fec = C5H5FeC5H4) 1 and FecC(OSiMe3)P(SiMe3) 2 have been obtained and characterized by X-ray single crystal structure analysis. Experiments for the preparation of FecCP 3 are reported.
引用
收藏
页码：716 / 722
页数：7
相关论文
共 50 条
  • [41] SYNTHESIS AND STRUCTURE OF MONO(CYCLOPENTADIENYL)-SUBSTITUTED AND BIS(CYCLOPENTADIENYL)-SUBSTITUTED FERROCENES
    PLENIO, H
    ORGANOMETALLICS, 1992, 11 (05) : 1856 - 1859
  • [42] Synthesis and properties of azole-substituted ferrocenes
    Mochida, Tomoyuki
    Shimizu, Hirotaka
    Suzuki, Shinya
    Akasaka, Takahiro
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (23) : 4882 - 4889
  • [43] Enantioselective ortho-lithiation of substituted ferrocenes
    Div. of Ener. and Hydrocarbon Chem., Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan
    J. Org. Chem., 3 (1172-1174):
  • [44] ANALYSIS OF SUBSTITUTED FERROCENES BY INFRARED-SPECTROSCOPY
    PHILLIPS, L
    LACEY, AR
    COOPER, MK
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (05): : 1383 - 1391
  • [45] Syntheses and Structures of 1,8,13,16-Substituted Triptycenes
    Schwartzen, Anna
    Rovers, Marla
    Neumann, Beate
    Stammler, Hans-Georg
    Mitzel, Norbert W.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (38) : 5323 - 5333
  • [46] Bis(boryl anion)-Substituted Pyrenes: Syntheses, Characterizations, and Crystal Structures
    Yuan, Ningning
    Wang, Wenqing
    Fang, Yong
    Zuo, Jiacheng
    Zhao, Yue
    Tan, Gengwen
    Wang, Xinping
    ORGANOMETALLICS, 2017, 36 (14) : 2498 - 2501
  • [47] Syntheses and structures of the first two tetra-scandium substituted polyoxometalates
    Cai, Zhen-Wen
    Liu, Bing-Xin
    Yang, Tao
    Li, Xin-Xiong
    Zheng, Shou-Tian
    INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 80 : 1 - 5
  • [48] SYNTHESES, STRUCTURES, AND REACTIONS OF PHENYLETHYNYL-SUBSTITUTED BICYCLO[3.3.0]OCTANES
    QUAST, H
    CARLSEN, J
    ROSCHERT, H
    PETERS, EM
    PETERS, K
    VONSCHNERING, HG
    CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (11): : 2591 - 2611
  • [49] Photoelectron spectroscopy of methyl-substituted ferrocenes.
    Darsey, GP
    Lichtenberger, DL
    Moberg, JK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 136 - INOR
  • [50] DYNAMIC BEHAVIOR OF SOME BORYL-SUBSTITUTED FERROCENES
    HERBERHOLD, M
    DORFLER, U
    WRACKMEYER, B
    POLYHEDRON, 1995, 14 (19) : 2683 - 2689
12345