SYNTHESES AND STRUCTURES OF FUNCTIONAL SUBSTITUTED FERROCENES

被引：10

作者：

GRUNHAGEN, A ^{[1
]}

PIEPER, U ^{[1
]}

KOTTKE, T ^{[1
]}

ROESKY, HW ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 04期

关键词：

N; O-BIS(TRIMETHYLSILYL)FERROCENYLIMIDATE; E; Z-(FERROCENYL-TRIMETHYLSILOXYMETHYLIDEN)TRIMETHYLSILYLPHOSPHANE;

D O I：

10.1002/zaac.19946200422

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Substituted ferrocenes have been prepared using carbonic acid chloride of ferrocene. New pathways have been found reacting the acid chloride with sodium hexamethyldisilazane and tris(trimethylsilyl)phosphane, respectively. The compounds FecC(OSiMe3)N(SiMe3) (Fec = C5H5FeC5H4) 1 and FecC(OSiMe3)P(SiMe3) 2 have been obtained and characterized by X-ray single crystal structure analysis. Experiments for the preparation of FecCP 3 are reported.

引用

页码：716 / 722

页数：7

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