A RADICAL-BASED SYNTHESIS OF (Z,Z)-TRICYCLOHEXAPRENOL

被引：15
|
作者：
HEISSLER, D
JENN, T
NAGANO, H
机构：
[1] Institut de Chimie, URA CNRS 31, Université Louis Pasteur, 67008 Strasbourg
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 51期
关键词：
TRICYCLOHEXAPRENOL; RADICAL ADDITION; ELIMINATION REACTION; CIS DOUBLE BOND FORMATION;
D O I：
10.1016/0040-4039(91)80541-D
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Addition of the isocopal-12-en-15-yl radical to a methyl 3-hydroxy-2-methylene alkenoate and stereoselective elimination of methanesulphonic acid from the mesylated adducts are the key steps of this synthesis of (Z,Z)-tricyclohexaprenol.
引用
收藏
页码：7587 / 7590
页数：4
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