Study on the Effect of Deposition Parameters on Characteristics of Electrochemically Synthesized Polyaniline and Poly O-toluidine

被引：0

作者：

Huque, Md Monimul ^{[1
]}

Haider, Md Golam ^{[2
]}

Rokonuzzaman, Shah Md ^{[2
]}

Nuri, Md Aksaruzzaman ^{[2
]}

机构：

[1] BUET, Dept Chem, Dhaka 1000, Bangladesh

[2] Bangladesh Natl Museum, Conservat Lab, Dhaka 1000, Bangladesh

来源：

ORIENTAL JOURNAL OF CHEMISTRY | 2018年 / 34卷 / 02期

关键词：

Polyaniline; Poly o-Toluidine; Oxidation; DTA-TGA; UV-Visible Spectra;

D O I：

10.13005/ojc/340221

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Polyaniline and poly o-toluidine were electrochemically synthesized form their respective monomers. Electropolymerization was carried out galvanostatically using two vertical platinum sheets as anode and cathode respectively at three different current densities viz. 5, 10 and 15 mA/cm(2). From the electrical conductivity data, UV-Visible spectra, DTA and TGA it is found that both the polymers have maximum electrical conductivity, minimum band gap energy and higher thermal stability when the polymerization is carried out at 10 mA/cm(2). It is thus concluded that there exists an optimum deposition rate for the electrode position of conducting polymer.

引用

页码：771 / 776

页数：6

共 50 条

[31] CHARGE DELOCALIZATION IN POLY(O-TOLUIDINE) FIBERS
WANG, YZ
JOO, J
HSU, CH
POUGET, JP
EPSTEIN, AJ
PHYSICAL REVIEW B, 1994, 50 (23): : 16811 - 16816
[32] Studies on the dielectric properties of poly(o-toluidine) and poly(o-toluidine-aniline) copolymer
John, H
Thomas, RM
Mathew, KT
Joseph, R
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (01) : 592 - 598
[33] Mechanochemically synthesized poly(o-toluidine)-intercalated montmorillonite nanocomposites as antituberculosis drug carriers
Verma, Anurakshee
Riaz, Ufana
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS AND POLYMERIC BIOMATERIALS, 2018, 67 (04) : 221 - 228
[34] Comparative studies of chemically synthesized and RF plasma-polymerized poly (o-toluidine)
Islam, Shama
Lakshmi, G. B. V. S.
Zulfequar, M.
Husain, M.
Siddiqui, Azher M.
PRAMANA-JOURNAL OF PHYSICS, 2015, 84 (04): : 653 - 665
[35] Electrical and spectroscopic characterization of p-toluene sulfonic acid doped poly(o-toluidine) and poly(o-toluidine) blends
Lakshmi, G. B. V. S.
Ali, Vazid
Kulriya, Pawan
Siddiqui, Azher M.
Husain, M.
Zulfequar, M.
PHYSICA B-CONDENSED MATTER, 2007, 392 (1-2) : 259 - 265
[36] Heterojunction of poly (o-toluidine) and silicon nanowires
El-Zohary, Salah E.
Shenashen, Mohamed. A.
Haleem, Ashraf M. Abdel
Tsuji, Akinori
Okamoto, Toshihiro
Haraguchi, M.
JOURNAL OF NANOPHOTONICS, 2015, 9
[37] Conducting blends of poly(o-toluidine) and poly(ester)urathane
Ghosh, P
Chakrabarti, AT
Kar, SB
Chowdhury, R
SYNTHETIC METALS, 2004, 144 (03) : 241 - 247
[38] Spectroscopic Characterization of Electrodeposited Poly(o-toluidine) Thin Films and Electrical Properties of ITO/Poly(o-toluidine)/Aluminum Schottky Diodes
Elmansouri, A.
Outzourhit, A.
Oueriagli, A.
Lachkar, A.
Hadik, N.
Achour, M.
Abouelaoualim, A.
Berrada, K.
Ameziane, E.
ACTIVE AND PASSIVE ELECTRONIC COMPONENTS, 2007, 2007
[39] Spectroscopic and Electrical Characterization of Doped Poly (o-toluidine)
Kumar, Anand
Ali, Vazid
Kumar, Sushil
Husain, M.
INTERNATIONAL CONFERENCE ON ADVANCES IN CONDENSED AND NANO MATERIALS (ICACNM-2011), 2011, 1393
[40] Preparation and sensor properties of poly (o-toluidine) film
Ergun Ekinci
Polymer Bulletin, 1999, 42 : 693 - 699

← 1 2 3 4 5 →