THE FORMATION OF HIGHLY DISPERSED SILVER BY THE REDUCTION OF AG+ IONS IN AQUEOUS-SOLUTIONS

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作者
ROGACH, AL
KHVALYUK, VN
GURIN, VS
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
摘要
A highly dispersed aqueous colloid of metallic silver was obtained by reducing AgNO3 with NaBH4. Stabilization of the silver sol was achieved by adding sodium trimetaphosphate, polyvinyl alcohol, or some nitrogen- and sulfur-containing surfactants. Small silver clusters were obtained by forming colloidal silver particles on a PVA-based polymer matrix, which impeded oxidation and coagulation of silver particles at early stages of reduction.
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页码:221 / 223
页数:3
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