ACID-CATALYZED COMPLEXATION OF ARENES WITH CR(CO)6

被引：5

作者：

HRNCIAR, P ^{[1
]}

TOMA, S ^{[1
]}

机构：

[1] COMENIUS UNIV BRATISLAVA,DEPT ORGAN CHEM,CS-84215 BRATISLAVA,SLOVAKIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80047-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several acids were tested as potential catalysts for complexation of arenes with Cr(CO)6 in boiling decalin. Acetic acid was found to be an efficient catalyst for complexation of acyl- and acyloxybenzenes. A mixture of butanone or cyclohexanone and acetic acid, with THF and acetic acid was found to be an efficient catalytic system or complexation of other arenes. The complex (eta-2-acenaphthylene)4Cr(CO)2 was isolated during an attempt on acetic acid catalysed complexation of acenaphthylene with Cr(CO)6.

引用

页码：161 / 164

页数：4

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