ACID-BASE PROPERTIES AND NUCLEOPHILICITY OF DECYLAMINE IN AQUEOUS MICELLAR SOLUTIONS OF CATIONIC SURFACTANTS WITH HYDROXYALKYL FRAGMENT IN THE HEAD GROUP

被引：0
|
作者：
Mirgorodskaya, A. B. [1 ]
Yatckevich, E. I. [1 ]
Lukashenko, S. S. [1 ]
机构：
[1] RAS, Inst Organ & Phys Chem AE Arbuzova KazNTs, St Acad Arbuzova 8, Kazan 120088, Russia
来源：
LIQUID CRYSTALS AND THEIR APPLICATION | 2009年 / 02期
关键词：
hydroxyalkylated surfactants; decylamine; hydrolysis; kinetics; mixed micelles;
D O I：
暂无
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The differences between the hydroxyalkylated surfactants and their trimethylammonium analogues observed in a course of the p-nitrophenylacetate hydrolysis reaction are due to the hydrogen bonding of the hydroxyalkyl substitutor with the substrate. From one side, decylamine, being introduced to the system, shows up as the nucleophilic reactant responsible for the aminolysis contribution to the total p-nitrophenylacetate destruction rate. On the other hand it facilitates micellization in the system via the mixed aggregates formation.
引用
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页码：13 / 20
页数：8
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