Bis{4-phenyl-1-[1-(pyridin-2-yl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}cadmium

被引：2
|
作者：
Fonseca, Alexandra de Souza [1 ]
Gervini, Vanessa Carratu [1 ]
Bresolin, Leandro [1 ]
Locateni, Aline [2 ]
de Oliveira, Adriano Bof [3 ]
机构：
[1] Univ Fed Rio Grande, Escola Quim & Alimentos, Ave Italia Km 08,Campus Carreiros, BR-96203900 Rio Grande, RS, Brazil
[2] Univ Fed Santa Maria, Dept Quim, Ave Roraima, BR-97105900 Santa Maria, RS, Brazil
[3] Univ Fed Sergipe, Dept Quim, Ave Marechal Rondon S-N, BR-49100000 Sao Cristovao, SE, Brazil
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812016558
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)(2)]. The Cd-II atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N-H center dot center dot center dot S interactions, building a one-dimensional hydrogen-bonded polymer along [0 (11) over bar].
引用
收藏
页码：M635 / +
页数：12
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