SINGLET AND TRIPLET EXCITONS IN CONJUGATED POLYMERS

被引:139
|
作者
ABE, S
YU, J
SU, WP
机构
[1] ELECTROTECH LAB,UMEZONO,TSUKUBA 305,JAPAN
[2] UNIV HOUSTON,DEPT PHYS,HOUSTON,TX 77204
来源
PHYSICAL REVIEW B | 1992年 / 45卷 / 15期
关键词
D O I
10.1103/PhysRevB.45.8264
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Exciton states in conjugated polymers are theoretically studied in the Su-Schrieffer-Heeger model supplemented by long-range Coulomb interactions. The relationship between exciton energies and basic interaction parameters is clarified, demonstrating the special nature of one-dimensional excitons. The binding energies of the lowest singlet and triplet excitons depend sensitively upon the on-site Coulomb energy. Relevant experiments in polydiacetylene can be explained by the present model using moderate interaction strength.
引用
收藏
页码:8264 / 8271
页数:8
相关论文
共 50 条
  • [41] EXCITONS AND OPTICAL NONLINEARITIES IN CONJUGATED POLYMERS
    WU, CQ
    COMMUNICATIONS IN THEORETICAL PHYSICS, 1994, 22 (03) : 257 - 264
  • [42] Theory of excitons and biexcitons in π-conjugated polymers
    Mazumdar, S
    Chandross, M
    PRIMARY PHOTOEXCITATIONS IN CONJUGATED POLYMERS: MOLECULAR EXCITON VERSUS SEMICONDUCTOR BAND MODEL, 1997, : 384 - 429
  • [43] Recombination of singlet excitons with geminate pairs of charge carriers in conjugated polymers -: art. no. 033104
    Romanovskii, YV
    Arkhipov, VI
    Bässler, H
    PHYSICAL REVIEW B, 2001, 64 (03)
  • [44] COMPETITION OF TRIPLET-TRIPLET AND TRIPLET-TRIPLET-SINGLET ENERGY TRANSFER IN POLYMERS
    ANISIMOV, V
    BURSHTEIN, K
    BOGOYAVL.
    KARPUKHIN, O
    OPTICS AND SPECTROSCOPY-USSR, 1970, 28 (04): : 438 - +
  • [45] Geminate and Nongeminate Recombination of Triplet Excitons Formed by Singlet Fission
    Bayliss, Sam L.
    Chepelianskii, Alexei D.
    Sepe, Alessandro
    Walker, Brian J.
    Ehrler, Bruno
    Bruzek, Matthew J.
    Anthony, John E.
    Greenham, Neil C.
    PHYSICAL REVIEW LETTERS, 2014, 112 (23)
  • [46] Spatial separation of triplet excitons drives endothermic singlet fission
    Korovina, Nadezhda V.
    Chang, Christopher H.
    Johnson, Justin C.
    NATURE CHEMISTRY, 2020, 12 (04) : 391 - +
  • [47] Spatial separation of triplet excitons drives endothermic singlet fission
    Nadezhda V. Korovina
    Christopher H. Chang
    Justin C. Johnson
    Nature Chemistry, 2020, 12 : 391 - 398
  • [48] Singlet-triplet and triplet-triplet interactions in conjugated polymer single molecules
    Yu, J
    Lammi, R
    Gesquiere, AJ
    Barbara, PF
    JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (20): : 10025 - 10034
  • [49] Triplet excitons, singlet fission, and prospects for improved organic photovoltaics
    Tauber, Michael
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [50] Dissociation processes of singlet and triplet excitons in organic photovoltaic cells
    Xu, Zhihua
    Wu, Yue
    Hu, Bin
    APPLIED PHYSICS LETTERS, 2006, 89 (13)