CROWN THIOETHER COMPLEXES OF P-BLOCK ELEMENTS - CRYSTAL AND MOLECULAR-STRUCTURES OF SBCL3.-1,4,7-TRITHIACYCLONONANE AND 2SBCL3.-1,4,7,10,13,16-HEXATHIACYCLOOCTADECANE

被引：36

作者：

WILLEY, GR

LAKIN, MT

RAVINDRAN, M

ALCOCK, NW

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first crown thioether complexes of Sb(III) and Bi(III), as representative p-block elements, have been isolated, viz SbCl3.9S3 1, BiCl3.9S3.0.5 MeCN, SbCl3.15S5, 2SbCl3.18S6 2 and BiCl3.18S6; + X-ray crystal structure determinations of 1 and 2 establish full participation of ligand S-donor sites in metal . . . sulphur bonding in each case.

引用

页码：271 / 272

页数：2

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