KINETIC AND EQUILIBRIUM STUDIES OF THE REACTION OF 2,4-DINITROPHENYL-2,4,6-TRINITROPHENYLMETHANE WITH CRYPTANDS IN ACETONITRILE

被引：6
|
作者：
BRZEZINSKI, B
JARCZEWSKI, A
LESKA, B
SCHROEDER, G
机构：
[1] Faculty of Chemistry, Adam Mickiewicz University, 60-780 Poznań
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1994年 / 318卷
关键词：
D O I：
10.1016/0022-2860(93)07900-H
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Deprotonation of 2,4-dinitrophenyl-2,4,6-trinitrophenylmethane (C-acid) by five cryptands, 221, 222, 222B, 22 and di(Ph-CH2)22, in acetonitrile has been studied by visible and H-1 NMR spectroscopy. The reaction of C-acid with the cryptands in acetonitrile solution gives a stable, asymmetric carbanion and a protonated base. Kinetic and equilibrium measurements for reactions of C-acid with five cryptands have been completed.
引用
收藏
页码：107 / 112
页数：6
相关论文
共 50 条
12345