Crystal structure of [Ag(NH3)(3)](2)[Ag(NH3)(2)](2)[SnF6]F-2, a compound showing argentophilic interactions

被引：0

作者：

Kraus, Florian ^{[1
]}

Fichtl, Matthias ^{[1
]}

Baer, Sebastian ^{[1
]}

机构：

[1] Philipps Univ Marburg, Anorgan Chem, Fluorchem, Fachbereich Chem, Hans Meerwein Str 4, D-35032 Marburg, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷

关键词：

crystal structure; silver; argentophilic interactions; fluorides; ammine ligand;

D O I：

10.1107/S2056989016019010

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Bis[triamminesilver(I)] bis[diamminesilver(I)] hexafluoridostannate(IV) difluoride, [Ag(NH3)(3)](2)[Ag(NH3)(2)](2)[SnF6]F-2, was obtained in the form of colourless crystals from the reaction of CsAgSnF7 in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the structure, i.e. a linear diammine and a T-shaped triammine complex. The ammine silver(I) complexes show Ag center dot center dot center dot Ag distances in the range of argentophilic interactions. In the crystal, several N-H center dot center dot center dot F hydrogen bonds are present between the complex cations and the SbF6- and F- anions, leading to the formation of a three-dimensional network.

引用

页码：1860 / +

页数：8

共 50 条

[31] The Reactions of Silver, Zirconium, and Hafnium Fluorides with Liquid Ammonia: Syntheses and Crystal Structures of Ag(NH3)2F•2NH3, [M(NH3)4F4]•NH3 (M =Zr, Hf), and (N2H7)F
Kraus, Florian
Baer, Sebastian A.
Fichtl, Matthias B.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (03) : 441 - 447
[32] Synthesis, Thermal Properties, and Crystal Structure of the Complex Ag2[Pd(NH3)2(SO3)2]
Mulagaleev, R. F.
Solov'ev, L. A.
Blokhin, A. I.
Nikulin, M. Ya.
Volkov, V. E.
Kirik, S. D.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (10) : 1524 - 1528
[33] Crystal structure of [UO2(NH3)(5)]NO3 center dot NH3
Woidy, Patrick
Kraus, Florian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1710 - +
[34] CRYSTAL-STRUCTURE AND SPECTRA OF NA4[NI(NH3)4] [AG(S2O3)2]2.NH3
STOMBERG, R
SVENSSON, IB
TOMLINSO.AA
ACTA CHEMICA SCANDINAVICA, 1973, 27 (04): : 1192 - 1202
[35] Synthesis and crystal structure of new amminecopper(II) nitrates: [Cu(NH3)(2)](NO3)(2) and [Cu(NH3)](NO3)(2)
Morozov, IV
Korenev, YM
Troyanov, SI
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (11): : 2003 - 2007
[36] The crystal structure of silver diamminotetranitro-cobaltiate (Ag[Co(NH3)(2)(NO2)(4)])
Wells, AF
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1936, 95 (1/2): : 74 - 82
[37] A re-interpretation of the crystal structure of '(NH4)2(NH3)[Ni(NH3)2Cl4]' in terms of (NH4)2-2z[Ni(NH3)2]z[Ni(NH3)2Cl4]
Leineweber, A
JOURNAL OF SOLID STATE CHEMISTRY, 2003, 176 (01) : 198 - 202
[38] The crystal structure of Hg(NH3)(2)Cl-2
Bijvoet, JM
MacGillavry, CH
NATURE, 1934, 134 : 849 - 850
[39] CRYSTAL-STRUCTURE OF PB2CL6[NH3(CH2)2NH3]
LOFVING, I
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1976, 30 (09): : 715 - 718
[40] CRYSTAL STRUCTURE OF [RUNO(OH)(NO2)2(NH3)2]
KHODASOV.TS
SERGIENK.VS
ACTA CRYSTALLOGRAPHICA, 1966, S 21 : A144 - &

← 1 2 3 4 5 →