RING CHAIN TRANSFORMATIONS .10. SYNTHESIS OF CONDENSED (OMEGA-AMINOALKYL)IMIDAZOLES BY RING CHAIN TRANSFORMATION

被引：0
|
作者：
BOHRISCH, J
PATZEL, M
LIEBSCHER, J
MAAS, G
机构：
[1] HUMBOLDT UNIV BERLIN,FACHBEREICH CHEM,HESS STR 1-2,O-1040 BERLIN,GERMANY
[2] UNIV KAISERSLAUTERN,FACHBEREICH CHEM,W-6750 KAISERSLAUTERN,GERMANY
来源：
SYNTHESIS-STUTTGART | 1993年 / 05期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2-Aminoazaheterocycles 1 react with lactam acetals (2,2-diethoxy-1-methylpyrrolidine, -1-methylpiperidine and -hexahydro-1-methyl-1H-azepine, 2) affording 2-lactamimino azaheterocycles 3. Reaction of the latter with CH-acidic methyl halides 4 allows a ring chain transformation via N-alkylation products 5 resulting in novel 2-[omega-(methylammonio)alkyl]imidazo[2,1-b]thiazole, -[1,2-a]pyridine and -[1,2-a]pyrimidine halides 7 and the corresponding 2-[omega-methylamino)alkyl] compounds 8.
引用
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页码：521 / 524
页数：4
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