DIPOLE DIPOLE INTERACTIONS NEAR INTERFACES

被引：25
|
作者：
URBAKH, M
KLAFTER, J
机构：
[1] School of Chemistry, Tel-Aviv University
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 13期
关键词：
D O I：
10.1021/j100115a042
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The nature of the pair interaction between dipoles embedded in a liquid in the vicinity of a nonmetallic interface is investigated in the continuum limit. It is shown that the dipole-dipole interaction can be significantly modified in the presence of a boundary in liquids characterized by a nonlocal dielectric function or in liquids whose dielectric properties change due to geometrical restrictions. Different limits are studied and relationships to experimental observables are discussed.
引用
收藏
页码：3344 / 3349
页数：6
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