MECHANISM OF AL-SUBSTITUTION FOR FE-SUBSTITUTION DURING THE ALPHA-(FE, AL)OOH-]GAMMA-(FE, AL)2O3 TRANSFORMATION

被引:5
|
作者
WOLSKA, E
SZAJDA, W
PISZORA, P
机构
[1] Department of Magnetochemistry, Adam Mickiewicz University, PL-60780 Poznań
关键词
D O I
10.1016/0167-2738(94)90368-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of aluminium ions on the crystal structure and magnetic characteristics of the final product and of intermediate phases appearing during the pseudomozphic transformation of the orthorhombic alpha-ferric hydroxide oxide in the tetragonal spinel gamma-ferric oxide were studied by X-ray powder diffraction, infrared spectroscopy and magnetic measurements. Solids solutions of the composition alpha-(Fe1-xAlx)1-y/3(OH)1+yO1-y were formed by incorporation of aluminium from the [Al(OH)4]-solution. The ordering of cationic vacancies and the tetragonal superstructure of gamma-(Fe, Al)2O3 were not affected by the substitution of aluminium for iron.
引用
收藏
页码:537 / 541
页数:5
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