RING-OPENING POLYMERIZATION OF METALLOCENOPHANES

被引：85
|
作者：
MANNERS, I
机构：
[1] Department of Chemistry, University of Toronto, Toronto, Ontario, M5S 1A1
来源：
ADVANCED MATERIALS | 1994年 / 6卷 / 01期
关键词：
D O I：
10.1002/adma.19940060115
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The development of processable high molecular weight polymers with skeletal transition metal atoms represents a synthetic challenge that, if overcome, can be expected to yield a variety of materials with novel electrical, optical, magnetic, or preceramic properties. Recent work has shown that the ring-opening polymerization (ROP) of strained, ring-tilted [1]- or [2]metallocenophanes provides a route to a variety of well-defined, ferrocene-backbone polymers with molecular weights of over 1000000 in several cases.
引用
收藏
页码：68 / 71
页数：4
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