THEORY OF GEMINATE RECOMBINATION OF RADICAL PAIRS WITH INSTANTANEOUSLY CHANGING SPIN HAMILTONIAN .3. RADICAL RECOMBINATION IN SWITCHED HIGH MAGNETIC-FIELD

被引：17
|
作者：
MIKHAILOV, SA
PURTOV, PA
DOKTOROV, AB
机构：
[1] RUSSIAN ACAD SCI,INST CHEM KINET & COMBUST,NOVOSIBIRSK 630090,USSR
[2] RUSSIAN ACAD SCI,INST WATER & ENVIRONM PROBLEMS,BARNAUL 656099,USSR
来源：
CHEMICAL PHYSICS | 1992年 / 166卷 / 1-2期
关键词：
D O I：
10.1016/0301-0104(92)87003-R
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The theory of the recombination of radical pairs (RPs) in a switched high magnetic field is proposed for the first time. The RP recombination probability is calculated for a stochastic motion of reagents in solution. Within the framework of a phenomenological two-positional model the analysis of the external field switching effect upon the recombination probability and CIDNP effects in the reaction products is carried out. It is shown that the switched magnetic field experiments contain information on the RP magnetic-resonance parameters as well as on kinetic ones. The above experiments are compared with the time-resolved ones, and the "effectiveness" of this kind of experiments is discussed.
引用
收藏
页码：35 / 49
页数：15
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