USE OF DIOXIRANES FOR THE CHEMOSELECTIVE OXIDATION OF TERTIARY-AMINES BEARING ALKENE MOIETIES

被引:38
|
作者
FERRER, M
SANCHEZBAEZA, F
MESSEGUER, A
DIEZ, A
RUBIRALTA, M
机构
[1] CSIC,CID,DEPT BIOL ORGAN CHEM,E-08034 BARCELONA,SPAIN
[2] UNIV BARCELONA,FAC PHARM,ORGAN CHEM LAB,E-08028 BARCELONA,SPAIN
关键词
D O I
10.1039/c39950000293
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A neat and high yield chemoselective epoxidation of alkene moieties present in tertiary amines is accomplished by treatment of the corresponding amine-boron trifluoride adduct with dimethyldioxirane or methyl(trifluoromethyl)dioxirane.
引用
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页码:293 / 294
页数:2
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