STRUCTURAL STUDY OF NEUTRAL-IONIC TRANSITION IN DMTTF-CA

被引：11
|
作者：
NOGAMI, Y [1 ]
TAODA, M [1 ]
OSHIMA, K [1 ]
AOKI, S [1 ]
NAKAYAMA, T [1 ]
MIURA, A [1 ]
机构：
[1] TOSHIBA RES & DEV CTR, KAWASAKI, KANAGAWA 210, JAPAN
来源：
SYNTHETIC METALS | 1995年 / 70卷 / 1-3期
关键词：
D O I：
10.1016/0379-6779(94)02826-K
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Dimethyltetrathiafulvalene-p-chloranil (DMTTF-CA), showing a particular neutral(N)-ionic(I) transition from a N phase into a N-I coexisting phase by cooling, was structural analyzed by X-ray at 29K, 48K, 109K and 293K Below Tc or 65K, changes observed in unit cell parameters, bond lengths and anisotropic temperature factors indicate 1) a increase in degree of charge transfer(CT) from a DMTTF donor to a CA acceptor and 2) a formation of a molecular dimerization, in I part of the coexisting phase. A possible staging superlattice was not observed.
引用
收藏
页码：1219 / 1220
页数：2
相关论文
共 50 条
  • [11] Evidence for a soft mode in the temperature induced neutral-ionic transition of TTF-CA
    Masino, M
    Girlando, A
    Soos, ZG
    CHEMICAL PHYSICS LETTERS, 2003, 369 (3-4) : 428 - 433
  • [12] THEORY OF NEUTRAL-IONIC TRANSITION IN MIXED STACK COMPOUNDS
    NAGAOSA, N
    TAKIMOTO, J
    SYNTHETIC METALS, 1987, 19 (1-3) : 497 - 502
  • [13] Role of Interchain Interactions in the Neutral-Ionic Phase Transition
    Girlando, Alberto
    CRYSTAL GROWTH & DESIGN, 2024, 24 (24) : 10358 - 10363
  • [14] THEORY OF THE NEUTRAL-IONIC TRANSITION IN TTF-CHLORANIL
    KOJYO, N
    ONODERA, Y
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1987, 56 (09) : 3228 - 3239
  • [15] NEUTRAL-IONIC TRANSITION IN DIMETHYL-TTP-CHLORANIL
    AOKI, S
    NAKAGAMA, T
    MIURA, A
    SYNTHETIC METALS, 1995, 70 (1-3) : 1243 - 1244
  • [16] Neutral-ionic transition in TTF(2)IA at high pressure
    Tasaki, K
    Matsuzaki, S
    Yartsev, VM
    SOLID STATE COMMUNICATIONS, 1997, 103 (06) : 365 - 369
  • [17] Neutral-ionic phase transition:: A thorough ab initio study of TTF-CA -: art. no. 035120
    Oison, V
    Katan, C
    Rabiller, P
    Souhassou, M
    Koenig, C
    PHYSICAL REVIEW B, 2003, 67 (03):
  • [18] Spectroscopic effects of neutral-ionic transition in TTF(2)IA
    Tasaki, K
    Matsuzaki, S
    Yartsev, VM
    PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1997, 203 (01): : 265 - 279
  • [19] Unified phase diagram of models exhibiting a neutral-ionic transition
    Legeza, Ö
    Buchta, K
    Sólyom, J
    PHYSICAL REVIEW B, 2006, 73 (16)
  • [20] Temperature-induced valence and structural instability in DMTTF-CA:: Single-crystal Raman and infrared measurements
    Ranzieri, Paolo
    Masino, Matteo
    Girlando, Alberto
    Lemee-Cailleau, Marie-Helene
    PHYSICAL REVIEW B, 2007, 76 (13):
12345